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4-hydroxy-3-methylbut-2-en-1-yl diphosphate synthase activity definition: Catalysis of the reaction: (E)-4-hydroxy-3-methylbut-2-en-1-yl diphosphate + H2O + protein-disulfide = 2-C-methyl-D-erythritol 2,4-cyclodiphosphate + protein-dithiol. Note that (E)-4-hydroxy-3-methylbut-2-en-1-yl diphosphate is an alternative way of naming 1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate. [EC:1.17.4.3, PMID:11752431]
3,4-dihydroxy-2-butanone-4-phosphate synthase activity definition: Catalysis of the reaction: ribulose-5-phosphate = 3,4-dihydroxy-2-butanone-4-phosphate + formate. [MetaCyc:DIOHBUTANONEPSYN-RXN]
(2,3-dihydroxybenzoyl)adenylate synthase activity definition: Catalysis of the reaction: ATP + 2,3-dihydroxybenzoate = diphosphate + (2,3-dihydroxybenzoyl)adenylate. [EC:2.7.7.58, MetaCyc:2.7.7.58-RXN]
3-deoxy-7-phosphoheptulonate synthase activity definition: Catalysis of the reaction: phosphoenolpyruvate + D-erythrose 4-phosphate + H2O = 2-dehydro-3-deoxy-D-arabino-heptonate 7-phosphate + phosphate. [EC:2.5.1.54]
3-deoxy-8-phosphooctulonate synthase activity definition: Catalysis of the reaction: phosphoenolpyruvate + D-arabinose 5-phosphate + H2O = 2-dehydro-3-deoxy-D-octonate 8-phosphate + phosphate. [EC:2.5.1.55]
1-deoxy-D-xylulose-5-phosphate synthase activity definition: Catalysis of the reaction: pyruvate + D-glyceraldehyde 3-phosphate = 1-deoxy-D-xylulose 5-phosphate + CO2. [EC:2.2.1.7]
2-hydroxyglutarate synthase activity definition: Catalysis of the reaction: propanoyl-CoA + H2O + glyoxylate = 2-hydroxyglutarate + CoA. [EC:2.3.3.11]
2-isopropylmalate synthase activity definition: Catalysis of the reaction: acetyl-CoA + 3-methyl-2-oxobutanoate + H2O = (2S)-2-isopropylmalate + CoA. [EC:2.3.3.13]
2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase activity definition: OBSOLETE. Catalysis of the reaction: 2-oxoglutarate + isochorismate = 2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + pyruvate + CO2. [EC:2.5.1.64, PMID:1459959]
2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase activity definition: Catalysis of the reaction: 5-enolpyruvoyl-6-hydroxy-2-succinylcyclohex-3-ene-1-carboxylate = (1R,6R)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate + pyruvate. [EC:4.2.99.20, MetaCyc:RXN-9310]
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